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Pentagonal bipyramidal molecular geometry
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Pentagonal bipyramidal molecular geometry : ウィキペディア英語版
Pentagonal bipyramidal molecular geometry

In chemistry, a pentagonal bipyramid (or dipyramid) is a molecular geometry with one atom at the centre with seven ligands at the corners of a pentagonal dipyramid. A perfect pentagonal bipyramid belongs to the molecular point group ''D5h''.
The pentagonal bipyramid is a case where bond angles surrounding an atom are not identical (see also Trigonal bipyramid molecular geometry). Other seven coordinate geometries include the mono-capped octahedron and mono-capped trigonal prism. A variety of transition metal complexes adopt heptacoordination, but the symmetry is usually lower than D5h.
==Examples==

* Iodine heptafluoride (IF7) with 7 bonding groups
* Peroxo Cr(IV)-complexes, e.g. () where the peroxo groups occupy four of the planar positions.

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